in Reflected Light
The basic instrument for petrographic examination of ‘ore’ minerals or ‘opaque’ minerals is the ore microscope, which is similar to a conventional petrographic microscope in the system of lenses, polarizer, analyzer and various diaphragms. An ore microscope however, differs from a petrographic one in that it has an incident light source rather than a substage transmitting one, which allows examination of polished surfaces of opaque minerals under reflected light.
Components of the Ore Microscope:
Though there are numerous models of ore microscopes, there are certain basic elements common to all. These are:
2. A circular stage graduated in degrees, that can be rotated through 360o, attached to the frame. This is usually equipped with a rack-and-pinion movement permitting it to be moved up and down for focusing the specimen, and a mechanical stage equipped with X and Y movement for systematic examination and point counting of grains in the specimen.
3. Objective lenses which are interchangeable and may be classed in terms of type (achromat, apochromat or fluorite), their magnification and numerical aperture, and whether they are for oil immersion or air usage.
4. The ocular serves to enlarge the primary image formed by the objective and render it visible to the eye. Oculars commonly contain cross hairs or a micrometer or a grid with a fixed rectangular pattern used for measuring particle sizes.
5. The standard illuminating system consists of two lenses, two or three diaphragms, a polarizer and an incandescent lamp of 6-12 V and 15-100 W. The illuminator aperture diaphragm restricts the field of view and stray scattered light. The illuminator field diaphragm controls the angle of the cone of light incident on the specimen and should be set to just enclose the field of view (this restricts the light to the most parallel rays, minimizes elliptical polarization and maximizes contrast). In many microscopes a third diaphragm helps sharpen the image.
6. The reflector is a means by which light is brought vertically onto the polished surface. Reflectors are of two types: the glass plate reflector and the half-field prism (see figure). Both types have their advantages and disadvantages. Many microscopes have both types mounted on a horizontal slide so that either may be used.
7. The polarizer is usually positioned within the illuminating system between the lamp and the collector lens but may also be located between the diaphragms. It is usually a calcite prism or a polaroid plate that renders light linearly polarized in a N-S orientation. The analyzer is a device similar to a polarizer but is positioned between the objective and ocular with its vibration directions perpendicular to those of the polarizer.
Accessories of the Ore Microscope:
Monochromators: The visible range of light lies between 400 to 700 nm, whereas the operable range of most microscopes extends several hundred nm above and below this range. Since the optical properties of minerals vary as a function of wavelength, it is sometimes necessary to provide light of a particular wavelength. This is commonly achieved by the use of:
a) Fixed monochromatic interference filters which consist of a glass plate on which alternating layers of low reflecting transparent diaelectric substances and higher reflecting semitransparent metal films or diaelectrics of high R.I. are deposited. Light passing through these filters is not truly monochromatic but lies within a narrow (<15 nm) band.
b) Continuous-spectrum monochromators are interference filters for which the wavelength of transmitted light varies continuously along the filter. A window, the width of which may be varied to control the passband width, may be slid along the monochromator to whatever wavelength is desired, thus providing monochromatic light over the entire visible range and even beyond.
Photometers: These are used to measure the reflectance of minerals. Most of them consist of a photomultiplier tube that has a high sensitivity throughout the visible spectrum. Photometers must be used in conjunction with stabilized light sources, high quality monochromators, and reflectance standards.
For accurate observation of optical properties, a proper adjustment of various elements of the microscope is extremely important. Although most adjustments are done at the factory, certain others must be made by the ore microscopist.
1. Place a polished section on the stage and center the objective / stage properly.
2. Replace the ocular with a pinhole eyepiece and close down the aperture diaphragm until its image is a small circle of light. Rotate the reflector until the image of the aperture diaphragm is at the center of the field.
3. Rotate the stage. If the image does not move, the polished section is level. If the image moves, the section should be leveled before proceeding.
4. Center the light source. Attach a low power objective to the microscope, throw out the analyzer and remove the ocular. The field of view should be evenly and brilliantly illuminated. If peripheral shadows appear, the light source is off center and must be adjusted by means of the centering screws.
5. Check the orientation of the axis of the reflecting device. Focus with a low power objective on a leveled polished surface. Close down the iris diaphragm until brilliant illumination of the field is restricted to the smallest possible bright spot. Now rotate the reflector on its axis. The bright spot should move across the field in a path precisely parallel to the N-S cross-hair of the ocular. If the path is at an angle, the axis of the reflector is not horizontal and needs correction.
The optical properties of ore minerals determinable under the microscope fall under two categories:
1. Properties observed in plane polarized light (without analyzer). These include color, reflectivity, bireflectance (= absorption, pleochroism or reflection pleochroism).
2. Properties observed between crossed nicols. These include isotropism vs. anisotropism, polarization colors and internal reflections. Besides these, other rotation properties viz., polarization figures and phase differences may be determined.
Color: Most ore minerals have colors ranging from pure white to gray, and only a few have definite tints of the spectral colors. The human eye has a poor memory for colors but at the same time it has a marvelous sensitivity to very slight differences in hue or brightness of adjacent objects. The apparent color of a mineral as seen under the microscope depends upon a number of factors, and as such is of limited diagnostic value by itself. Factors affecting the apparent color of a mineral are:
5. Index of refraction of the immersion medium.
Reflectivity: is the ratio of the intensity of light reflected by a mineral to the intensity of the light incident upon it, expressed in per cent (R or R%). Reflectance of minerals varies as a function of the following:
Quantitative reflectance measurements are done with various types of photometers, but rough visual estimates may be made and minerals in a section may be arranged in an order of increasing or decreasing reflectance. Eg. Quartz (5%), magnetite (20%), galena (43%), pyrite (55%).
Bireflectance: Most minerals of the non isometric groups show changes in reflectance or color (or tint) or both when sections of certain orientations are rotated. These properties are collectively termed bireflectance. In some literature, bireflectance refers only to change in reflectivity and reflection pleochroism is the term used to describe a change in color. All sections of the cubic minerals and basal sections of the hexagonal and tetragonal crystals do not exhibit these properties. In addition to noting this property it is usual to note the intensity (e.g. very strong, strong, moderate, weak, very weak) with which these properties are exhibited. The following are some examples of bireflecting minerals:
° Strong - graphite, molybdenite, covellite, stibnite, valleriite.
° Moderate - marcasite, hematite, niccolite, cubanite, pyrrhotite.
° Weak - ilmenite, enargite, arsenopyrite.
Weak or very weak bireflectance in minerals may be identified by closely observing adjacent grains.
Anisotropism: Polished sections of non-isotropic minerals when rotated through 360o under ‘crossed’ nicols will show either a) complete darkness, or b) faint illumination with no change in intensity or color of illumination. Such minerals are termed isotropic. Minerals crystallizing in the non-isometric systems will show a change in the intensity of illumination or color of illumination (or both) in white light. Such minerals are termed anisotropic. Sections of certain special orientations of anisotropic minerals (e.g. the basal sections of hexagonal and tetragonal crystals) may be isotropic. As with pleochroism, the anisotropy can range from a maximum to zero depending upon the orientation of the section, and therefore the terms very weak, weak, moderate, strong and very strong are used to describe it. Anisotropy is best observed under intense illumination using a plane glass reflector and a low power ocular. In cases of weak anisotropy, the effects may be detectable only when a number of adjacent grains of a mineral are minutely examined while rotating the stage. Observation of anisotropy may be more easily accomplished by either a) throwing the analyzer slightly off from the precise crossed position, or b) leaving the stage stationary and slowly rotating the analyzer 5-10o back and forth through its crossed position.
NOTE: Fine parallel scratches of improper polishing or careless buffing can produce effects similar to pleochroism and anisotropy
polarization colors: The change in color of a mineral during rotation under crossed nicols produces a beautiful effect. These are the polarization colors. The polarization colors of certain minerals are highly characteristic and extremely useful in identification. However they are used less than they deserve to be for several reasons:
° The colors are constant only if the nicols are precisely crossed, which is rarely the case.
° Polarization colors appear different to different observers, hence the difficulty in applying precise color terms.
° The intensity and hue of polarization colors varies from microscope to microscope.
° Constant illumination is necessary for consistent results.
Internal Reflections: Translucent minerals, when observed under reflected light, allow light to penetrate beneath the surface and be reflected back to the observer from cracks, crystal boundaries, cleavages and other flaws within the crystal. Such light will appear as diffuse areas or patches known as internal reflections. Although visible in plane polarized light, internal reflections are best seen under crossed nicols and intense illumination using oil immersion and high power magnification. They are best seen at the edges of grains or in fine grains. It is important to note that many grains of a mineral that could show internal reflections may not exhibit them. Both the occurrence and colors of internal reflections are of diagnostic value. The following are some examples:
Sphalerite Yellow to brown (sometimes red to green)
Cinnabar Blood red
Proustite-pyrargyrite Ruby red
Rutile Clear yellow to deep red-brown
Cassiterite Yellow brown to yellow
Hematite Blood red
Wolframite Deep brown
The physical properties of ore minerals observed in polished sections are of great assistance in mineral identification, and hence their study is routine in ore microscopy. The most useful and easily observable physical properties are crystal form and habit, cleavage and parting, twinning, zoning, inclusions and intergrowths and hardness.
Crystal Form and Habit: Some ore minerals, particularly the harder ones viz., pyrite, hematite, wolframite, arsenopyrite, cobaltite and magnetite have a remarkable power of crystallization and develop well formed crystals even under adverse conditions. The softer minerals, e.g. chalcopyrite, galena, tetrahedrite and pyrargyrite have somewhat lower powers of crystallization and form crystals only in open spaces. Since a polished surface shows two dimensional sections rather than whole crystals, the shape as seen in a polished section depends upon the manner the crystal is intersected by the polished surface. Thus cubes appear rectangular or triangular of various shapes; hexagonal prisms appear hexagonal or rectangular, etc., so that the crystal form must be mentally reconstructed from observations of a number of crystals of a particular mineral.
Terms used in mineralogy e.g. cubic, octahedral, acicular, radiating, columnar, bladed, tabular, foliate, micaceous, concentric, colloform, prismatic, fibrous, etc. are appropriate for describing crystal form and habit as seen in polished sections.
Zoning: Many ore minerals exhibit zonal growth in the form of concentrically shelled structure indicating deposition in successive layers around a nucleus. The shells may be few or many and thin or thick. Zoning is sometimes visible in ordinary light due to color contrasts, physical discontinuities or zonally arranged inclusions. In other cases zoning is visible only in crossed nicols or after etching with an appropriate chemical. Zoning in minerals is due to either of the following reasons:
2. changes in the rate of growth
3. Simultaneous crystallization of more than one mineral at certain stage / stages.
4. Variation in the composition of successively deposited layers.
Galena, sphalerite, pyrite, stibnite, cobaltite, safflorite and arsenopyrite are some of the many minerals that show zonal structure.
Cleavage and Parting: In polished surfaces the cleavages of minerals are not as well developed as in thin sections. Cleavage or parting is evident in the form of one or more sets of parallel, distinct or indistinct cracks. Minerals may exhibit one to three sets of cleavages depending upon the number of sets present and the orientation of the polished surface with respect to these. The presence of three or more sets of cleavages may give rise to triangular pits usually arranged in rows parallel to one set. Such pits are characteristic of galena, and may also be present in magnetite, pentlandite, gersdorffite, etc. A prismatic cleavage gives rise to diamond-shaped, triangular or rectangular patterns; a pinacoidal cleavage gives rise to a set of parallel cracks.
Cleavage of a mineral may not be evident in a well polished surface, or in minerals occurring in fine grained aggregates. It is likely to be more evident in slightly weathered ores, during the earlier stages of polishing, at the margins of grains, or after etching.
Twinning: Three major types of twinning may be observed in ore minerals seen in polished sections - growth, inversion and deformation. Twinning is best seen in anisotropic minerals under crossed polars. In isotropic minerals it is generally not visible unless the surface is etched. It is sometimes evident from abrupt changes in the orientation of cleavages or of rows of inclusions. The crystallographic planes involved in twinning are usually not determinable in polished sections. Nevertheless, the twin patterns in some minerals are quite characteristic e.g. "arrowhead" twins (growth) in marcasite, lamellar twins (deformation) in hematite and chalcopyrite and "oleander leaf" twins (inversion) in chalcopyrite, stannite and acanthite.
Inclusions and Intergrowths: Inclusions of one or more minerals in another is a very common feature of ores. The characteristics of inclusions depends to some extent on the mode of formation of the guest and the host. They may have either of the following modes of formation:
In so far as the mode of occurrence is concerned, inclusions may:
Intergrowths refer to simultaneous deposition of one mineral with another. The term also covers graphic and subgraphic arrangements of two minerals, or exsolutions in which the two minerals are intimately associated and neither can be said to be the host. A knowledge of inclusions is useful in deciphering the paragenetic sequence while that of intergrowths in identification since the number of mineral combinations is limited. This is particularly true of exsolution intergrowths.
Hardness: The term hardness as used in ore microscopy refers to a number of phenomenon. Three types of hardnesses are particularly important - polishing, scratch and microindentation. It is important to note that these three forms are not entirely equivalent, being the response to different kinds of deformation or abrasion. Only the polishing hardness shall be discussed here.
Polishing hardness is the resistance of a particular mineral to abrasion during the polishing process. The fact that hard minerals are worn away more slowly than soft minerals means that they may stand slightly above the surface of softer grains giving rise to an effect called "polishing relief".
Polishing hardness can be examined under a standard ore microscope by comparing the relative hardness (i.e. relief) of adjacent phases and can be very helpful in mineral identification. The determination involves a simple test using the Kalb light line, a phenomenon analogus to the Becke line used in transmitted light. The procedure is as follows:
Usually the polishing hardness of an unknown mineral is compared to one or several known minerals. This permits the mineral to be arranged in a sequence of increasing or decreasing polishing hardness with other known minerals, and can be of great assistance in mineral identification.